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Chemical reactions generally take place in solution and often involve ions. The behaviour of ions in solution, manifested through ion solvation, is therefore of prime interest in chemistry. This book considers in depth the phenomenology of ion solvation and the models and interpretations that have been proposed as the physical causes for the observed phenomena. It contains a thorough discussion of the statistical thermodynamic background of the solvation process from which a discussion of the actual thermodynamics is developed. This, in turn, serves as a background to the structural and kinetic features of ion solvation. The book begins by considering the relatively simple case of interactions between an ion and few solvent molecules in the gas phase, and proceeds to deal with solvation in a bulk solvent with well-known properties (water), solvation in bulk nonaqueous solvents, selective solvation in solvent mixtures and solvation in competition with ion-ion interactions. These concepts are illustrated in the final chapter of the book by many examples of applications. Included in the text are numerous tables of data which will enable the reader to use the book not only as a monograph but also as a reference volume. The applications considered cover a wide range of fields - electrochemistry, hydrometallurgy, separation chemistry and organic chemistry.

The Properties of Solvents Yizhak Marcus Hebrew University of Jerusalem, Israel The Properties of Solvents contains extensively annotated tables of physical, chemical and related properties for over 250 solvents. Factual knowledge of solvent effects on solvation, solubility, chemical equilibria and reaction rate is important for theoretical and practical applications. This volume will enable chemists to choose solvents rationally, taking into account solvent properties and the expected results. The Properties of Solvents is a valuable source of information for all who are interested in the behaviour of solutions. These include solution, organic, analytical and physical chemists. Contents * Introduction * Solvent effects * Physical properties * Chemical properties * Applications The Wiley Series in Solution Chemistry fills the increasing need to present authoritative, comprehensive and fully up-to-date accounts of the many aspects of solution chemistry. Internationally recognized experts from research or teaching institutions in various countries are invited to contribute to the series.

The Properties of Solvents Yizhak Marcus Hebrew University of Jerusalem, Israel The Properties of Solvents contains extensively annotated tables of physical, chemical and related properties for over 250 solvents. Factual knowledge of solvent effects on solvation, solubility, chemical equilibria and reaction rate is important for theoretical and practical applications. This volume will enable chemists to choose solvents rationally, taking into account solvent properties and the expected results. The Properties of Solvents is a valuable source of information for all who are interested in the behaviour of solutions. These include solution, organic, analytical and physical chemists. Contents * Introduction * Solvent effects * Physical properties * Chemical properties * Applications The Wiley Series in Solution Chemistry fills the increasing need to present authoritative, comprehensive and fully up-to-date accounts of the many aspects of solution chemistry. Internationally recognized experts from research or teaching institutions in various countries are invited to contribute to the series.