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This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.

Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.

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Number 88 in the well-known Oxford Chemistry Primer series introduces upper-undergraduate students to how the three-dimensional shapes of molecules influence their chemical and physical properties. It starts with an introduction to common stereochemical terms used throughout the book. Chapter two covers the structures of simple unstrained organic molecules followed by examples of strained molecules. The third chapter deals with conformational analysis of acyclic and carbocyclic molecules, ending with a short exposition of molecular mechanics. Chapter four is about stereoisomerism in molecules and compounds. A full description of enantiomerism and diastereomerism is followed by an explanation of the nomenclature for absolute and relative configurations of molecules and for topism. The book concludes with a survey of stereoselective and stereospecific reactions, including the use of chiral catalysts and auxiliaries, rules for predicting stereoselectivity, and double asymmetric synthesis.

Topics in Stereochemistry, Materials-Chirality provides comprehensive information on the stereochemistry of materials. Coverage includes the chirality of materials and the important role stereochemistry plays in the physical properties of polymers, liquid crystals, and other materials.

Stereoisomers are compounds with the same chemical formula and connectivity but with different arrangements of their atoms in 3-dimensional space. Stereochemistry encompasses the study of stereoisomers and their properties. Despite having an identical chemical formula, stereoisomers can have drastically different biological, medicinal, and chemical properties. Basic Organic Stereochemistry explains in clear, concise terms the concepts and properties of stereoisomers. Ideal both as a text for advanced undergraduate or graduate students and as a handy guide for researchers in industry, this superb text covers: Polarimetry and optical rotation Internal coordinates, configuration, and conformation Nature of stereoisomers Barriers between stereoisomers and residual stereoisomers Symmetry operators and symmetry point groups Properties of stereoisomers and stereoisomer discrimination Separation of stereoisomers, resolution, and racemization Suitable for students in organic and biological chemistry, Basic Organic Stereochemistry is unparalleled as a convenient text.

Stereoisomers are compounds with the same chemical formula and connectivity but with different arrangements of their atoms in 3-dimensional space. Stereochemistry encompasses the study of stereoisomers and their properties. Despite having an identical chemical formula, stereoisomers can have drastically different biological, medicinal, and chemical properties. Basic Organic Stereochemistry explains in clear, concise terms the concepts and properties of stereoisomers. Ideal both as a text for advanced undergraduate or graduate students and as a handy guide for researchers in industry, this superb text covers: Polarimetry and optical rotation Internal coordinates, configuration, and conformation Nature of stereoisomers Barriers between stereoisomers and residual stereoisomers Symmetry operators and symmetry point groups Properties of stereoisomers and stereoisomer discrimination Separation of stereoisomers, resolution, and racemization Suitable for students in organic and biological chemistry, Basic Organic Stereochemistry is unparalleled as a convenient text.

A unique guide to variable temperature CD spectroscopy and its application in organic chemistry This timely, original, thought-provoking work looks at organic stereochemistry from the perspective of circular dichroism (CD), using variable temperature CD spectroscopy to determine the conformation or absolute configuration of chiral molecules. With an emphasis on the analysis of optically active ketones and the carbonyl chromophore, the authors demonstrate the advantages of this highly sensitive spectroscopic tool for obtaining stereochemical information in diverse areas of organic chemistry, biochemistry, and medicinal/pharmaceutical chemistry. They combine detailed examples of stereochemical analysis with clear, thorough presentations, correlating chiroptical data with molecular mechanics calculations as well as data from NMR spectroscopy and other spectroscopic techniques. In addition, they provide a systematic survey of the professional literature, featuring an extraordinary collection of original CD spectra run at varying temperatures. Coverage includes: * Chiroptical measurements: CD and ORD (Optical Rotatory Dispersion) * Conformational analysis of compounds ranging from simple cyclic ketones to polycyclics * Conjugated and homoconjugated systems * Stereochemistry of the carbon-carbon double bond * Stereochemistry from exciton coupling of two or more chromophores * An interesting historical account of the development of stereochemical concepts

Offering a comprehensive narrative of the early history of stereochemistry, Dr Ramberg explores the reasons for and the consequences of the fundamental change in the meaning of chemical formulas with the emergence of stereochemistry during the last quarter of the nineteenth century. As yet relatively unexplored by historians, the development of stereochemistry - the study of the three-dimensional properties of molecules - provides a superb case study for exploring the meaning and purpose of chemical formulas, as it entailed a significant change in the meaning of chemical formulas from the purely chemical conception of 'structure' to the physico-chemical conception of molecules provided by the tetrahedral carbon atom. This study is the first to treat the emergence of the unique visual language of organic chemistry between 1830 and 1874 to place in context the near simultaneous proposal of the tetrahedral carbon atom by J.H. van 't Hoff and J.A. Le Bel in 1874. Dr Ramberg then examines the research programs in stereochemistry by Johannes Wislicenus, Arthur Hantzsch, Victor Meyer, Carl Bischoff, Emil Fischer and Alfred Werner, showing how the emergence of stereochemistry was a logical continuation of established research traditions in chemistry. In so doing, he also illustrates the novel and controversial characteristics of stereochemical ideas, especially the unprecedented use of mechanistic and dynamic principles in chemical explanation.

A unique guide to variable temperature CD spectroscopy and its application in organic chemistry This timely, original, thought-provoking work looks at organic stereochemistry from the perspective of circular dichroism (CD), using variable temperature CD spectroscopy to determine the conformation or absolute configuration of chiral molecules. With an emphasis on the analysis of optically active ketones and the carbonyl chromophore, the authors demonstrate the advantages of this highly sensitive spectroscopic tool for obtaining stereochemical information in diverse areas of organic chemistry, biochemistry, and medicinal/pharmaceutical chemistry. They combine detailed examples of stereochemical analysis with clear, thorough presentations, correlating chiroptical data with molecular mechanics calculations as well as data from NMR spectroscopy and other spectroscopic techniques. In addition, they provide a systematic survey of the professional literature, featuring an extraordinary collection of original CD spectra run at varying temperatures. Coverage includes: * Chiroptical measurements: CD and ORD (Optical Rotatory Dispersion) * Conformational analysis of compounds ranging from simple cyclic ketones to polycyclics * Conjugated and homoconjugated systems * Stereochemistry of the carbon-carbon double bond * Stereochemistry from exciton coupling of two or more chromophores * An interesting historical account of the development of stereochemical concepts

The critically acclaimed laboratory standard, Methods in Enzymology, is one of the most highly respected publications in the field of biochemistry. Since 1955, each volume has been eagerly awaited, frequently consulted, and praised by researchers and reviewers alike. The series contains much material still relevant today - truly an essential publication for researchers in all fields of life sciences.

Offering a comprehensive narrative of the early history of stereochemistry, Dr Ramberg explores the reasons for and the consequences of the fundamental change in the meaning of chemical formulas with the emergence of stereochemistry during the last quarter of the nineteenth century. As yet relatively unexplored by historians, the development of stereochemistry - the study of the three-dimensional properties of molecules - provides a superb case study for exploring the meaning and purpose of chemical formulas, as it entailed a significant change in the meaning of chemical formulas from the purely chemical conception of 'structure' to the physico-chemical conception of molecules provided by the tetrahedral carbon atom. This study is the first to treat the emergence of the unique visual language of organic chemistry between 1830 and 1874 to place in context the near simultaneous proposal of the tetrahedral carbon atom by J.H. van 't Hoff and J.A. Le Bel in 1874. Dr Ramberg then examines the research programs in stereochemistry by Johannes Wislicenus, Arthur Hantzsch, Victor Meyer, Carl Bischoff, Emil Fischer and Alfred Werner, showing how the emergence of stereochemistry was a logical continuation of established research traditions in chemistry. In so doing, he also illustrates the novel and controversial characteristics of stereochemical ideas, especially the unprecedented use of mechanistic and dynamic principles in chemical explanation.

Dr. Eliel gained fame for his forty years of research in stereochemistry and conformational analysis. He tells of a fascinating life beginning with his flight from Nazi Germany through his worldwide studies and work at Notre Dame and the University of North Carolina. Included in this volume are many photographs and discussion of his scientific studies.

Pericyclic reactions constitute a major strand of organic chemistry, including such commercially important synthetic reactions as the Diels-Alder reaction. Reactions such as these are characterised by their predictable stereochemistry and cyclic transition structures. This primer reviews these reactions in order to explain their theoretical basis via correlation diagrams. It also shows students how to recognize the different types of pericyclic reaction, their mechanisms, and their applications to organic synthesis.The text is part of the renowned Oxford Chemistry Primer series, which provides focused introductions to a range of important topics in chemistry. The series has been refreshed and updated to suit the needs of today's students and instructors. The rigorous, yet accessible, the texts include cutting-edge examples and relevant applications. Pedagogical features provided in the primers--including questions at the end of every chapter, diagrams, margin notes, suggestions for further reading, and an expansive glossary--encourage active learning and promote understanding.

Topics in Stereochemistry, Materials-Chirality provides comprehensive information on the stereochemistry of materials. Coverage includes the chirality of materials and the important role stereochemistry plays in the physical properties of polymers, liquid crystals, and other materials.

Get all you need to know with Super Reviews! Each Super Review is packed with in-depth, student-friendly topic reviews that fully explain everything about the subject. The Organic Chemistry I Super Review includes structure and properties, alkanes, alkenes, alkynes, alkyl halides, stereochemistry, cyclic hydrocarbons, aromatic hydrocarbons, aryl halides, ethers and epoxides, alcohols and glycols, carboxylic acids, and carboxylic acid derivatives. Take the Super Review quizzes to see how much you've learned - and where you need more study. Makes an excellent study aid and textbook companion. Great for self-study!DETAILS- From cover to cover, each in-depth topic review is easy-to-follow and easy-to-grasp - Perfect when preparing for homework, quizzes, and exams!- Review questions after each topic that highlight and reinforce key areas and concepts- Student-friendly language for easy reading and comprehension- Includes quizzes that test your understanding of the subject

An easy formula for success. With topics such as stereochemistry, carboxylic acids, and unsaturated hydrocarbons, it’s no wonder so many students have a bad reaction to organic chemistry class. Fortunately, this guide gives college students who are required to take organic chemistry an accessible, easy-to-follow companion to their textbooks. · With the tremendous growth in the health-care job market, many students are pursuing college degrees that require organic chemistry · Ian Guch is an award-winning chemistry teacher who has taught at both the high school and college levels

This book presents key aspects of organic synthesis – stereochemistry, functional group transformations, bond formation, synthesis planning, mechanisms, and spectroscopy – and a guide to literature searching in a reader-friendly manner. ·    Helps students understand the skills and basics they need to move from introductory to graduate organic chemistry classes ·    Balances synthetic and physical organic chemistry in a way accessible to students ·    Features extensive end-of-chapter problems ·    Updates include new examples and discussion of online resources now common for literature searches ·    Adds sections on protecting groups and green chemistry along with a rewritten chapter surveying organic spectroscopy

This book presents key aspects of organic synthesis – stereochemistry, functional group transformations, bond formation, synthesis planning, mechanisms, and spectroscopy – and a guide to literature searching in a reader-friendly manner. ·    Helps students understand the skills and basics they need to move from introductory to graduate organic chemistry classes ·    Balances synthetic and physical organic chemistry in a way accessible to students ·    Features extensive end-of-chapter problems ·    Updates include new examples and discussion of online resources now common for literature searches ·    Adds sections on protecting groups and green chemistry along with a rewritten chapter surveying organic spectroscopy