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The first truly comprehensive account of this versatile field. Classified and well-documented, it covers: * the chemistry of SNAr substitutions and anionic o-complexes * nucleophilic aromatic photosubstitutions * the possible role of electron transfer in some substitution processes * the ANRORC reactions The volume also discusses for the first time the whole field of nucleophilic aromatic substitutions of hydrogen, a subject of considerable recent interest. Researchers and students alike will appreciate the book's balanced presentation of mechanistic and synthetic features.

CONTENTS: (1) Structure, Relativity and Mechanism (2) Energetics, Kinetics and the investigation of mechanism (3) The strength of acides and bases (4) Nucleophilic substitution at a saturated carbon atom (5) Carbonium ions and electron-deficient N and O atoms (6) Electrophilic and nucleophilic substitution in aromatic systems (7) Electrophilic and nucleophilic addition to C=C (8) Nucleophilic addition to C=O (9) Eliminations (10) Carbanions (11) Radicals (12) Symmetry controlled reactions (13) Linear free energy relationships.